Chemistry: analytical and immunological testing – Sulfur containing – Sulfur dioxide
Patent
1983-05-09
1985-02-12
Turk, Arnold
Chemistry: analytical and immunological testing
Sulfur containing
Sulfur dioxide
324308, 324315, 436172, 436173, 556410, 556428, C07F 710, G01N 2164, G01N 2177, G01N 2408
Patent
active
044991908
ABSTRACT:
(CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy.
REFERENCES:
patent: 3973911 (1976-08-01), Von Smolinski et al.
patent: 4459421 (1984-07-01), Spicer et al.
Davis et al., Chemical Abstracts, vol. 93, 1980, p. 989, No. 93, 71846m.
Bennett et al., Chemical Abstracts, vol. 95, 1981, p. 681, No. 95, 150743v.
Dyer, "Applications of Absorption Spectroscopy of Organic Compounds", Prentice-Hall, Inc., 1965, pp. 58-66.
Griffins, R. G., Anal. Chem., 1977, 49,951a.
Davis et al., Inorg. Chem., 1980, 19, 2191-2192.
Bennett et al., J. Am. Chem. Soc. 1981, 103, 5522-5526.
Debrun et al., Chem. Abstracts, vol. 78, 1973, p. 267, No. 151907n.
Bennett Dennis W.
Davis Jon F.
Spicer Leonard D.
Rees Walter L.
The United States of America as represented by the United States
Turk Arnold
Weinberger James W.
LandOfFree
Method of detecting sulfur dioxide does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Method of detecting sulfur dioxide, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method of detecting sulfur dioxide will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1390005