Method of dehydrogenating cyclohexenone

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3706

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049335073

ABSTRACT:
Phenol is produced by dehydrogenating cyclohexenone through a vapor-phase reaction in the presence hydrogen using a solid-phase catalyst having platinum and alkali metal carried on a support.

REFERENCES:
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patent: 3149166 (1964-09-01), Poehler et al.
patent: 3256348 (1966-06-01), Schlossman
patent: 3534110 (1970-10-01), Jugun et al.
patent: 3801651 (1974-04-01), Adolphen et al.
Article entitled: "Halogenation with Copper(II), II, Unsaturated Ketones" by Kosower and Wu; in J. Org. Chem., vol. 28, pp. 633-638. (1963).
Article entitled: "Nouvelle Methode D'Armoatisation de Cyclohexenones Contenues Dans des Systemes Polycycliques" by Bondon, Pietrasanta and Pucci in Tetrahedron Letters, No. 10, pp. 821-824, 1977.
Article entitled: "An Improved Method for the Preparation of 2-Cyclohexen-1-One by Sharma, Sethi and Dev, in Synthesie", pp. 45-46 (1974).
Article in J. Org. Chem., vol. 36, pp. 752-757, entitled "A New Method for the Preparation of .alpha.,.beta.-Unsaturated Carbonyl Compounds" by Theissen.

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