Method of corrosion prevention

Distillation: apparatus – Apparatus – Elements

Reexamination Certificate

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Details

C106S014120, C106S014210, C159SDIG015, C159SDIG020, C159SDIG021, C203S007000, C203S051000, C203S086000, C252S389200, C568S913000, C034S427000

Reexamination Certificate

active

08057642

ABSTRACT:
This invention relates to a process for reducing the corrosion rate of iron-containing vessels within an ethylene glycol distillation system. The inventive process includes the addition of an additive component of sodium nitrite and sodium hypophosphite into such iron-containing vessels, to thereby react with iron of the inside walls and form a protective coating thereon. This process reduces the corrosion rate in iron-containing vessels of the apparatus, and reduces the catalytic effects of iron corrosion products within the system. Thus, not only is the on-stream time of the vessels extended, but also product quality is improved by reducing the aldehyde content of the final ethylene glycol product.

REFERENCES:
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patent: 5294371 (1994-03-01), Clubley et al.
patent: 5753316 (1998-05-01), Brent et al.
patent: 5788857 (1998-08-01), Yang et al.
patent: 6066232 (2000-05-01), Mohr et al.
patent: 6133489 (2000-10-01), Mohr et al.
patent: 6770222 (2004-08-01), Ukita et al.
patent: 2006-36449 (2006-02-01), None

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