Method of converting amine hydrohalide into free amine

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Preparing inorganic compound

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205552, 205338, 205349, 205431, 204522, 204539, 204541, C25B 100, C25B 300, C25B 700, C25B 1500

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active

059001330

ABSTRACT:
Describes a method of electrochemically converting amine hydrohalide, e.g., ethyleneamine hydrochloride, into free amine, e.g., free ethyleneamine. A three compartment electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and anion exchange membrane, (2) an anolyte compartment containing an anode assembly comprising an anode and a cation exchange membrane, and (3) an intermediate compartment separated from the catholyte and anolyte compartments by the anion and cation exchange membranes respectively. An aqueous solution of amine hydrohalide is charged to the catholyte compartment, while hydrogen halide solutions are charged to the intermediate and anolyte compartments. Direct current is passed through the electrolytic cell and an aqueous solution comprising free amine is removed from the catholyte compartment.

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