Method of coating an electrospray emitter

Radiant energy – Ionic separation or analysis – With sample supply means

Reexamination Certificate

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C250S282000, C250S281000

Reexamination Certificate

active

07446311

ABSTRACT:
The present invention provides a method of coating an electrospray emitter with silver and then gold utilizing wet-coating processes. First, the electrospray emitter is immersed in a silver-containing liquid solution to coat the electrospray emitter in a layer of silver. Next, the silver-coated electrospray emitter is removed from the silver solution and rinsed with water. The silver-coated electrospray emitter is then annealed to stabilize the silver layer. Once the silver layer has been stabilized, the silver-coated electrospray emitter is immersed into a gold-containing liquid solution and a voltage is applied. This voltage serves to electrochemically deposit a gold layer onto the silver layer. The gold- and silver-coated electrospray emitter is then removed from the gold-containing liquid solution and rinsed with water and, preferably, with nitric acid.

REFERENCES:
patent: 7007710 (2006-03-01), Heller et al.
patent: 2003/0141392 (2003-07-01), Nilsson et al.
patent: 2004/0245463 (2004-12-01), Wood et al.
patent: 2007/0252083 (2007-11-01), Arscott et al.
Barnidge, D. R., Nilsson, S., Markides, K. E., Rapp, H., Hjort, K., Rapid Commun. Mass Spectrom. 1999, 13, 994-1002.

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