Method of adding amines to 1,3 dienes

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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Details

252431P, 26029351, 260583H, C07D29502, C07D21114, C07C 8724

Patent

active

041044711

ABSTRACT:
A method of producing 1:2 amine-diene adducts which method comprises contacting a sterically unhindered amine with a 1,3 diene in the presence of a catalytic amount of a catalyst comprising an olefin-palladium complex preferably of the type X--Pd--X where X is an olefin and Pd is palladium in its zero valent state.

REFERENCES:
patent: 3435058 (1969-03-01), Rinehart
patent: 3479379 (1969-11-01), Ketley
patent: 3530187 (1970-09-01), Shryne
patent: 3891684 (1975-06-01), Jung

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