Method for vapor-phase catalytic oxidation of tert.-butyl alcoho

Details Method for vapor-phase catalytic oxidation of tert.-butyl alcoho Method for vapor-phase catalytic oxidation of tert.-butyl alcoho

1974-08-29

1976-05-04

Sutto, Anton H.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252437, 252439, 260531R, 260604R, C07C 5126, C07C 4516

Patent

active

039548562

ABSTRACT:
Oxidation of tert.-butyl alcohol is accomplished by contacting said alcohol with a tungsten-molybdenum-tellurium-nickel catalyst in the vapor phase at an elevated temperature in the presence of oxygen, in order to produce methacrolein and methacrylic acid. The catalyst desirably contains phosphorus and/or antimony in addition to the elements mentioned above.

REFERENCES:
patent: 3470239 (1969-09-01), Russell
patent: 3642930 (1972-02-01), Cranelli et al.
patent: 3829476 (1974-08-01), Yamada et al.
March, Advanced Organic Chemistry (1968) pp. 753-755.

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