Method for treating radioactive solutions

Compositions – Radioactive compositions

Patent

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210682, 210759, 210912, G21F 910, G21F 912, G21F 916

Patent

active

043404995

ABSTRACT:
Concentrated liquid waste solutions containing radioactive substances and also complex formers is treated by maintaining pH 5 and adding KMnO.sub.4 to oxidize complex formers, and solidifying and embedding the resultant solution in a binder. Dilute solutions are also maintained at a pH of 5 and excess KMnO.sub.4 added. The excess MnO.sub.4.sup.- is reduced to MnO.sub.2 by addition MnSO.sub.4. MnO.sub.2 separates and adsorbs radionuclides Mn-54, Sb-124, Sb-125 and 65-Zn contained in the solution.

REFERENCES:
patent: 2769780 (1956-11-01), Clifford et al.
patent: 3013978 (1961-12-01), Rosinski
patent: 3272738 (1966-09-01), Pitzer et al.
patent: 3873362 (1975-03-01), Mihram et al.
patent: 4226640 (1980-10-01), Bertholdt
Pavlik et al., "Treatment of High Detergent Content Radioactive Wastewater", Chem. Abs. 87:140673t (1977).
Verot et al., "Problems Posed by the Treatment of Effluents . . .", Chem. Abs. 71:15872a (1969).

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