Method for the recovery of uranium values from uranium tetrafluo

Specialized metallurgical processes – compositions for use therei – Processes – Electrothermic processes

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423 3, 423 18, 423 20, 423253, C22B 6002

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active

044128614

ABSTRACT:
The invention is a novel method for the recovery of uranium from dry, particulate uranium tetrafluoride. In one aspect, the invention comprises reacting particulate uranium tetrafluoride and calcium oxide in the presence of gaseous oxygen to effect formation of the corresponding alkaline earth metal uranate and alkaline earth metal fluoride. The product uranate is highly soluble in various acidic solutions wherein the product fluoride is virtually insoluble therein. The product mixture of uranate and alkaline earth metal fluoride is contacted with a suitable acid to provide a uranium-containing solution, from which the uranium is recovered. The invention can achieve quantitative recovery of uranium in highly pure form.

REFERENCES:
patent: 2733125 (1956-01-01), Spiegler
patent: 2795499 (1957-06-01), Peterson
patent: 3288595 (1966-11-01), Reichard
patent: 3842155 (1974-10-01), Muller et al.
patent: 4012493 (1977-03-01), Layne et al.
Chemical Abstracts #84: 127,823k, "Reaction of Platonium, Uranium, and Rare Earth Fluorides with Certain Metal Oxides in Fluoride Melts".
Chemical Abstracts #89: 32,737z, "Dissolution of Uranium in Calciothermic and Magnesiothermic Slags".

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