Method for the production of perfluoroalkyl phosphines and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus halides

Reexamination Certificate

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C562S818000, C568S008000

Reexamination Certificate

active

10511554

ABSTRACT:
The invention relates to a method for producing perfluoroalkyl phosphines, comprising at least one step in which at least one fluoro(perfluoroalkyl)phosphorane is reacted with at least one hydride ion donator, and the use of tris(perfluoroalkyl)phos-phines as perfluoroalkylating reactants.

REFERENCES:
patent: 4701569 (1987-10-01), Tordeux et al.
patent: 6096926 (2000-08-01), Roques et al.
patent: 2827285 (2003-01-01), None
Kampa et al., The Synthesis of Tris(perfluoroalkyl)phosphanes, Angewandte Chemie, 1995, 34 (11), 1241-44.
Mahmood et al., Comparative study of tris(trifluoromethyl)phosphine oxide, tris(nonafluorobutyl)phosphine oxide and fluorobis(nonafluorobutyl)phosphine oxide with ammonia and amines, Inorg. Chem.; 1988; 27(17); 2913-2916.
Gilje et al., Preparation and nuclear magnetic resonance parameters of perfluoroalkyl-substituted phosphorus(V) hydrides, Journal of the Chemical Society, Chemical Communications, 1973, 813-814.
Kampa J J: “The Synthesis of tris (Perfluoroalkyl) Phosphanes” Angewandte Chemie. International Edition, Verlag Chemie. Weinheim, DE, Bd. 34, Nr. 11, 1996, Seiten 1241-1244.

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