Method for the production of organosilicon compounds...

Details Method for the production of organosilicon compounds... Method for the production of organosilicon compounds...

2011-03-08

2011-03-08

Sullivan, Daniel M (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C205S420000

Reexamination Certificate

active

07902392

ABSTRACT:
Organosilicon compounds bearing carboxylic acid groups are easily and economically replaced in high yield by oxidation of a carbinol-functional organosilicon compound with an oxidizer in the presence of a moderator at a pH≧3. Carboxyl-functional organopolysiloxanes highly useful as textile softeners may be obtained by this method.

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English Abstract corresponding to EP 1 302 456 A1.
Anelli, et al.: “Fast and Selective Oxidation of Primary Alcohols to Aldehydes or Tocarboxylic Acids and of Secondary Alcohols to Ketones Mediated by Oxoammonium Salts under Two-Phase Conditions”, Journal of Organic Chemistry, American Chemical Society. Easton, US, vol. 52, No. 12, Jun. 12, 1987, pp. 2559-2562.
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