Method for the production of levulinic acid and its derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

549429, 549488, 549489, 560174, C07D 5100

Patent

active

060546115

ABSTRACT:
A method of producing dehydration products from one more 5-carbon or 6-carbon sugars includes reacting said one or more sugars at 40-240.degree. C. for 1 to 96 hours in the presence of 5-90% sulfuric acid, separating the reaction products, and recovering levulinic acid. The sugars are can be generated from strong acid hydrolysis of biomass, such as rice straw, paper, cotton and other cellulosic materials.

REFERENCES:
patent: 2206311 (1940-07-01), Thompson
patent: 2270328 (1942-01-01), Moyer
patent: 2305738 (1942-12-01), Scheuing et al.
patent: 2813900 (1957-11-01), Dunlop et al.
patent: 2840605 (1958-06-01), Leonard
patent: 3701789 (1972-10-01), Ramos-Rodriguez
patent: 4236021 (1980-11-01), Hsu et al.
patent: 4897497 (1990-01-01), Fitzpatrick
patent: 5562777 (1996-10-01), Farone et al.
The hydrogenation of 2-furaldehyde and its derivatives. G. Natta, R. Rigamonti and E. Beati, 23, 117-23 (1941), Chemical Abstracts, vol. 35, p. 5488-5489.
Levulinic acid. Wendell W. Moyer (to A.E. Staley Mfg. Co.). U.S. 2,270,328, Jan. 20, 10-Organic Chemistry, p. 3190.
Levulinic acid. Georg Scheuing and Wilhelm Konz (vested in the Alien Property Custodian). U.S. 2,305,738, Dec. 22, Chemical Abstracts, vol. 37, p. 3252.
Levulinic acid. Walter N. Haworth and Leslie F. Wiggins. Brit. 583,533, Dec. 20, 1946, Chemical Abstracts, 1947, p. 3123.
Derivatives of valerolactone, 1, 4-pentanediol, and 1, 4-bis (2-cyanoethoxy) pentane. Robert V. Christian, J. Am. Chem. Soc. 69, 1961-3 (1947), 10-Organic Chemistry, p. 6873-6874.
Levulinic acid. Holzhydrolyse Akt.-Ges. Ger. 700,643, Nov. 28, 1940, 10-Organic Chemistry, p. 6981.
Levulinic acid. Holzhydrolyse Akt.-Ges. Ger. 705,578, Mar. 27, 1941, Chemical Abstracts, vol. 36, p. 2079.
Levulinic acid. Alva Thompson (to Corn Products Refining Co.). U.S. 2,206,311, Jul., 2., Chemical Abstracts, vol. 34, p. 7299.
Organic Chemistry by Paul Karrer, Second English Edition, 1946, Elsevier Publishing Company, Inc., New York, Furan p. 737.
Furfural as a new decompotition product of glucose solution under oxygen atmosphere, Letters to the Editor, J. Pharm. Pharmac., 1978, 30, p. 668.
Practical Organic Chemistry including Qualitative Organic Analysis by Arthur I. Vogel, Third Edition, 1962, John Wiley & Sons, Inc., New York, N.Y., pp. 461-463.
Reagents for Organic Synthesis, Louis F. Fieser, 1967, John Wiley and Sons, Inc., New York, N.Y., pp. 564-566.
The Journal of the American Chemical Society, vol. LII, Sep.-Dec., 1930 by Arthur B. Lamb, "Levulinic Acid and its Esters" by Peter P.T. Sah and Shao-Yuan Ma, Dec. 18, 1930, vol. 52, pp. 4880-4883.
Levulinic acid recovery. Alexander D. Macallum (to E.I. du Pont de Nemours & Co.). U.S. 2,257,389, Sep. 30. Chemcial Abstracts, vol. 36, p. 99.
USPTO CNIDR, U.S. Patent 4,236,021, Nov. 25, 1980, Abstract for "Process for the manufacture of levulinic acid and esters".
Levulinic Acid as a Basic Chemical Raw Material, Reid H. Leonard, Industrial and Engineering Chemistry, vol. 48, No. 8, Aug. 1956, pp. 1330-1341.
Takahashi, J. Agr. Chem. Soc. Japan, vol. 20, 1944, pp. 553-556.
Database WPI: Section Ch. Week 9439: Derwent Publications Ltd., London, GB; Class B02, AN 94-315178; XP002060828 & SU 1 817 770 A (AS SIBE Chem Techn Inst Org Materials); May 23, 1993.
Effect of heat on aqueous solutions of sucrose and other carbohydrates. R. Montgomery and L.F. Wiggins, J. Soc. Chem. Ind. 66, 31-2 (1947); Chemical Abstracts, vol. 41, Col. 4025.
Interpretation of some reactions in the carbohydrate field in terms of consecutive electron displacement. Horace S. Isbell, J. Research Natl. Bur. Standards 32, 45-59 (1944); Chemical Abstracts, vol. 38, Col. 2319.
Thermochemical Pretreatment of Lignocellulose to Enhance Methane Fermentation: I. Monosaccharide and Furfurals Hydrothermal Decomposition and Product Formation Rates. K. Baush and P. McCarty, Biotechnology and Bioengineering, vol. 31, pp. 50-61 (1988).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Method for the production of levulinic acid and its derivatives does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method for the production of levulinic acid and its derivatives, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method for the production of levulinic acid and its derivatives will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-994519

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.