Method for the production of glyceric acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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C562S470000

Reexamination Certificate

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06844467

ABSTRACT:
Glyceric acid compounds of the formula (I)in-line-formulae description="In-line Formulae" end="lead"?R1R2C(OH)—CR3(OH)—COOX  (I)in-line-formulae description="In-line Formulae" end="tail"?where R1, R2and R3are independently hydrogen, C1-12-alkyl, C6-12-aryl, C7-13-alkaryl or C7-13-aralkyl andX is hydrogen, an alkali metal, an alkaline earth metal/2 or NH4,are prepared by saponification of glycidic acid compounds of the formula (II)where Y is NH2or OR4in which R4is C1-12-alkyl or C7-13-aralkyl,with ring-opening addition of water onto the epoxide ring.Preferably, Y is NH2and the glycidamide of the formula (II) which is used is prepared by reacting acrylonitriles of the formula (III)in-line-formulae description="In-line Formulae" end="lead"?R1R2C═CR3CN  (III)in-line-formulae description="In-line Formulae" end="tail"?with hydrogen peroxide.

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Database Crossfire Beilstein 'Online! Beilstein Institut zur Foerderung der Chemischen Wissenschaften, Frankfurt am Main, DE Database accession No. 356606, XP002206284.
Database Crossfire Beilstein 'Online! Beilstein Institut zur Foerderung der Chemischen Wissenschaften, Frankfurt am Main, DE Database accession No. 329484, XP002206285.
Database Crossfire Beilstein 'Online! Beilstein Institut zur Foerderung der Chemischen Wissenschaften, Frankfurt am Main, DE Database accession No. 282014, XP002206286.

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