Method for the production of alken-2-ol-1 or of alken-2-ol-1 and

Details Method for the production of alken-2-ol-1 or of alken-2-ol-1 and Method for the production of alken-2-ol-1 or of alken-2-ol-1 and

1977-06-06

1978-10-24

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

2603459R, 260462R, 568828, 568829, 568857, 568858, C07C 2912, C07F 504, C07D30906, C07D30918

Patent

active

041222911

ABSTRACT:
Production of an alken-2-ol-1, or of an alken-2-ol-1 and an alkanol-1 from the corresponding alken-3-ol-1 is described. The above compound or compounds can be produced with good selectivity by converting an alken-3-ol-1 to the boric acid ester, and, then, contacting the ester with a palladium catalyst in the presence of hydrogen or, alternatively, by carrying out the latter-mentioned step under conditions favorable to the formation of said boric acid ester and, thereafter, subjecting the reaction product to solvolysis.

REFERENCES:
patent: 2055437 (1936-09-01), Groll et al.
patent: 2537753 (1952-03-01), O'Conner et al.
patent: 3028431 (1962-04-01), Webb
patent: 3117153 (1964-01-01), Aldridge et al.
patent: 3188354 (1965-06-01), Roming
patent: 3244752 (1966-04-01), Eschinasi
patent: 3407227 (1968-10-01), Beck et al.
patent: 3655735 (1972-04-01), Pommer et al.
patent: 3974504 (1976-03-01), Kyo et al.

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