Method for the production of...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C546S098000

Reexamination Certificate

active

10510579

ABSTRACT:
A process for preparing perylene-3,4:9,10-tetracarboxylic diimides of the general formula Icomprisingdimerizing a naphthalene-1,8-dicarboximide of the formula IIin a reaction medium consisting essentially of an apolar aprotic organic solvent and an alkali metal base and subsequently reoxidizing the resulting alkali metal salt of the leuco form of the perylene-3,4:9,10-tetracarboxylic diimide in the presence of a polar solvent.

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Sakamoto, Takaaki et al. “Oxidative Coupling Reaction of 1,8-Naphthalimide a new synthetic methodology for the production of Perylene-3,4,9,10-Tetracarboximide”, Kawamura Rikagaku Kenkyusho Hokoku, vol. 8, pp. 85-95, with English abstract & full English translation 1997.
Sakamoto, Takaaki et al. “A ‘Green’ Route to Perylene Dyes: Direct Coupling Reactions of 1,8-Naphthalimide and Related Compounds under Mild Conditions Using a “New” Base Complex Reagent, t-BuOK/DBN”, J. Org. Chem. vol. 66, pp. 94-98 2001.
Jankowski, Z. et al. “Syntheses and Properties of Some Derivatives of N-[4′-(1,2,3-Benzotriazolyl)-phenyl]-naphthalimide”, Pol. J. Chem, vol. 55, No. 3, pp. 565-563 (abstract only) 1981.
Ganin, E.V. et al. “N-Substituted Isonaphthalimides. Peculiarities of Their Formation and Their Reaction with Amines”, Zh. Org. Khim. vol. 21, No. 11, pp. 2415-2423 (abstract only) 1985.

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