Method for the preparation of ketones

Details Method for the preparation of ketones Method for the preparation of ketones

1987-01-08

1988-06-28

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568385, 568342, C07C 4529

Patent

active

047540737

ABSTRACT:
Method for the preparation of ketones, by means of oxydation of the corresponding secondary alcohols, characterized in that said alcohols are catalytically oxidized by H.sub.2 O.sub.2 inside a two-phase system comprising:

REFERENCES:
patent: 4171313 (1979-10-01), Mares et al.
patent: 4480135 (1984-10-01), Esposito et al.
Venturello et al., J. Org. Chem.; vol. 48, pp. 3831-3833 (1983).
Venturello et al., Chem. Abst.; vol. 104, #27804t (1985).
Agrawal et al., Chem. Abst.; vol. 102, #173251k, (1985).
Bortalini et al., Chem. Abst.; vol. 103, #122757t, (1985).
Barry M. Trost and Yoshiro Masuyama, "Molybdenum Catalyzed Reactions Selectivity in Oxidations with Hydrogen Peroxide and Ammonium Molybdate", Israel Journal of Chemistry, vol. 24, 1984, pp. 134-143.
S. E. Jacobson, D. A. Muccigrosso, and F. Mares, "Oxidation of Alcohols by Molybdenum and Tungsten Peroxo Complexes," Journal of Organic Chemistry, vol. 44, No. 6, 1979, pp. 921-924.

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