Method for the preparation of crystalline and zeolitic aluminosi

Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing

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423326, C01B 3334

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051006367

ABSTRACT:
Disclosed herein is a method of preparing crystalline, zeolitic aluminosilicates with SiO.sub.2 /Al.sub.2 O.sub.3 ratios of 20 or more. The method provides a two-stage crystallization process which avoids the formation of secondary crystalline phases. The first stage is conducted at a temperature between 240.degree. C. and 325.degree. C. for between about 1 and 20 minutes. The second stage is conducted in an open vessel at a temperature between about 50.degree. C. and 100.degree. C. for about 40 to 240 hours.

REFERENCES:
patent: 3702886 (1972-11-01), Argauer et al.
patent: 4687654 (1987-08-01), Taramasso et al.
patent: 4818509 (1989-04-01), Dwyer et al.
P.A. Jacobs et al.: "Studies in surface science and catalysis", vol. 33, Synthesis of high-silica aluminosilicate zeolites, 1987, Elsevier, Amsterdam, pp. 113, 134-146.

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