Method for the preparation of complexes of metals of the VIII gr

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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260676R, 260680R, 260596, B01J 3130

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active

040628035

ABSTRACT:
A method is disclosed for preparing complexes of metals of the VIII Group of the Periodic Table, useful as hydrogenation catalysts. The method, as a single-step process, comprises reacting a polymeric complex containing V Group elements and VIII Group metal compounds directly with a metal atom which is directly bound to the V group element in the presence of a reducing substance. The reducing substance is selected among alkali metal and alkaline earth metal hydrides, mixed alkaline-III group element hydrides, organic metallic compounds of III Group metals, alkali metal and alkaline earth metal alkyls, Grignard compounds.

REFERENCES:
patent: 3553181 (1971-01-01), Delbouille et al.
patent: 3872026 (1975-03-01), Dunn
patent: 3974095 (1976-08-01), Volpin et al.
J. Org. Chem., 28 (July, 1963), pp. 1947-1948.

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