Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1986-09-09
1988-02-23
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
556451, 556453, 556454, 556455, 556456, C07F 708
Patent
active
047271728
ABSTRACT:
An efficient method is proposed for the preparation of an organosiloxane oligomer represented by the general formula YSi(R.sup.1).sub.n (--O--SiR.sub.3).sub.3-n, in which each of the groups denoted by R and R.sup.1 is a halogen-substituted or unsubstituted monovalent hydrocarbon group having 1 to 8 carbon atoms, Y is a hydrogen atom or a monovalent group selected from methyl, phenyl, vinyl, chloromethyl and 3-(meth)acryloxypropyl groups and n is zero, 1 or 2, by the reaction of an organosilicon halomagnesium salt of the formula R.sub.3 Si--O--MgX, in which X is a halogen atom, and an organosilane compound of the general formula YSi(R.sup.1).sub.n (Z).sub.3-n, in which Z is a halogen atom or a lower alkoxy group. In particular, tetrasiloxane compounds represented by the general formula Y.sup.1 Si[--O--Si(CH.sub.3).sub.2 (CH.sub.2 CH.sub.2 CF.sub.3)].sub.3, in which Y.sup.1 is a hydrogen atom, chloromethyl group or 3-methacryloxypropyl group, are each a novel compound not known in the prior art.
REFERENCES:
patent: 2961425 (1960-11-01), Pierce et al.
patent: 3006878 (1961-10-01), Talcott
patent: 3377371 (1968-04-01), Quaal
Ishihara Toshinobu
Kurosaki Tadao
Takamizawa Minoru
Yamamoto Akira
Goldberg Jules E.
Shaver Paul F.
Shin-Etsu Chemical Co. , Ltd.
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