Method for the preparation of a triazole compound

Details Method for the preparation of a triazole compound Method for the preparation of a triazole compound

1995-12-22

1996-10-22

Morris, Patricia L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D24912

Patent

active

055678254

ABSTRACT:
The improvement proposed in the invention consists in the use of, as a reaction solvent in the reaction of a 1,3,5-trialkyl-2-halogenobenzene and an alkali metal salt of 3-mercapto-1H-1,2,4-triazole in the presence of a copper catalyst for the preparation of a 3-(2,4,6-trialkylphenylthio)-1H-1,2,4-triazole useful as an intermediate in the preparation of herbicide compounds, a compound represented by the general formula ##STR1## in which R is a lower alkyl group, Y is a methylene group or an N-(lower alkyl)imino group and Z is a divalent hydrocarbon group to form a 5-membered ring or 6-membered ring together with the group --N--CO--Y--, such as N-methyl-2-pyrrolidone, N,N'-dimethyl-2-imidazolidinone and N,N'-dimethyl propylene urea, so as to obtain the product in a high yield without the danger of explosion.

REFERENCES:
patent: 3119877 (1964-01-01), Campbell et al.
patent: 5338720 (1994-08-01), Takeuchi et al.
Chemical Abstracts, vol. 121, No. 7, p. 1175, abstract No. 205358m(abstract of JP-A-06 080 651) (1994).
Chemical Abstracts, vol. 111, No. 25, p. 789, abstract No. 232788b (abstract of JP-A-01 121 279) (1989).
Methoden der Organischen Chemie, (Houben-Weyl), Band E11, Organische Schwefel-Verbindungen, Georg Thiem Verlag (Stuttgart), p. 174 (1985).
M. Fieser, Fieser and Fieser's Reagents for Organic Synthesis, vol. 11, Wiley-Interscience (New York), pp. 202-203 (1974).

Affiliated with

Also associated with

Rating

Method for the preparation of a triazole compound does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method for the preparation of a triazole compound, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method for the preparation of a triazole compound will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2359569