Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1984-02-27
1985-07-16
Evans, J. E.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
585250, C07C 2917, C07C 509
Patent
active
045298254
ABSTRACT:
The trans-isomer of an ethylenically unsaturated organic compound of the formula R.sup.1 CH.dbd.CHR.sup.2, in which R.sup.1 and R.sup.2 are each a substituted or unsubstituted monovalent hydrocarbon group, is selectively prepared in a high yield by the reduction of the corresponding acetylenically unsaturated organic compound of the formula R.sup.1 C.tbd.CR.sup.2. The method comprises reducing the starting compound in a hydrocarbon solvent containing an alkali metal dispersed therein in the presence of a proton donor compound such as an alcohol or a carboxylic acid at a temerature of 50.degree. to 150.degree. C.
REFERENCES:
patent: 2777884 (1957-01-01), Rutledge et al.
patent: 3225110 (1965-12-01), Kurtz
Ishihara Toshinobu
Yamamoto Akira
Evans J. E.
Shin-Etsu Chemical Co. , Ltd.
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