Method for the preparation of 1,3-oxathiolanes

Details Method for the preparation of 1,3-oxathiolanes Method for the preparation of 1,3-oxathiolanes

1988-09-09

1990-11-27

Berch, Mark L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549 30, 549 31, C07D49710, C07D32704, C07D41110

Patent

active

049737058

ABSTRACT:
A method for preparation of 1,3-oxathiolanes is described. The method comprises reacting, in a solvent, a fluoride ion source, a carbonyl compound, and a halomethyl trimethylsilylmethyl sulfide, wherein the halomethyl trimethylsilyl methyl sulfide is selected from a group consisting of chloromethyl trimethylsilylmethyl sulfide, bromomethyl trimethylsilylmethyl sulfide, or iodomethyl trimethylsilylmethyl sulfide.

REFERENCES:
patent: 4496600 (1985-01-01), Parliment
Hosomi, J.C.S. Chem. Comm., 1987, 1442.

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