Method for the methane chemical conversion into C.sub.2 hydrocar

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis

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585415, 585417, 585418, 585654, 585656, 585658, 585943, C07C 200, C07C 282, C07C 283

Patent

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057637229

ABSTRACT:
An improved method for the oxidative conversion of methane into higher hydrocarbons in which methane and oxygen are continuously and simultaneously cofed into a reaction zone under effective oxidative coupling conditions and contacted with a solid catalyst consisting essentially of a catalyst having a composition of empirical formula Ce.sub.a Na.sub.b Ca.sub.100 O.sub.x wherein a is in the range 0.03 to 2.0, b is in the range of 0.7 to 7.0 and oxygen is present in a molar amount sufficient to fulfill the valence requirements of cerium, sodium and calcium.

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patent: 4801762 (1989-01-01), Leyshon
patent: 4822944 (1989-04-01), Brazdil, Jr. et al.
patent: 4950836 (1990-08-01), Kimble et al.
patent: 4982041 (1991-01-01), Campbell

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