Method for the manufacture of methyl tertiary butyl ether from t

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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203 29, 203 45, 203 46, 203 73, 568698, 568699, C07C 4106, C07C 4109, C07C 4134, B01D 300

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058115978

ABSTRACT:
Methyl tertiary butyl ether is prepared from contaminated TBA by reactively distilling the contaminated TBA in a reactive distillation column to provide a lower boiling isobutylene fraction and a higher boiling aqueous TBA fraction, by distilling the higher boiling aqueous TBA fraction to provide a lower boiling TBA fraction, by charging the lower boiling isobutylene fraction, the lower boiling tertiary butyl alcohol fraction and methanol to an etherification reactor to form an etherification reaction product, by distilling the etherification reaction product to provide a lower boiling fraction containing isobutylene, methanol and methyl tertiary butyl ether by charging the lower boiling fraction to a finishing reactor to react the isobutylene and methanol contained therein to from additional MTBE and by recovering MTBE from the etherification reaction product and the isobutylene conversion product.

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patent: 5563301 (1996-10-01), Preston et al.
patent: 5565068 (1996-10-01), Parker et al.
patent: 5659091 (1997-08-01), Peters et al.

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