Liquid purification or separation – Processes – Chemical treatment
Reexamination Certificate
2002-06-10
2004-08-03
Hruskoci, Peter A. (Department: 1724)
Liquid purification or separation
Processes
Chemical treatment
C075S335000, C075S338000, C210S765000, C261S093000
Reexamination Certificate
active
06770207
ABSTRACT:
SUMMARY
The invention relates to a method for the leaching of solid matter from a sludge with the aid of a gas containing oxygen, whereby the solid matter of the sludge is reticulated in a tall reactor equipped with a central pipe in the centre of the reactor and a double-action mixer located in the vicinity of the lower edge of the central pipe. A flaw is formed with the aid of the mixer which sucks the sludge from the central pipe downward, and a gas to be conducted into the sludge in the bottom part of the reactor is dispersed in the form of small bubbles into the sludge outside the central pipe; and the flow direction of the sludge is turned upwards in the outer casing of the reactor.
The present invention relates to a method for the leaching of solid matter from a sludge with the aid of a gas containing oxygen, whereby the solid matter of the sludge is recirculated in a tall reactor equipped with a central pipe in the centre of the reactor and a double-action mixer located in the vicinity of the lower edge of the central pipe. A flow is formed with the aid of the mixer which sucks the sludge from the central pipe downward, and a gas to be conducted into the sludge in the bottom part of the reactor is dispersed in the form of small bubbles into the sludge outside the central pipe and the flow direction of the sludge is turned upwards in the outer casing of the reactor.
In leaching of a sludge containing solid matter, such as for example metal concentrate, it is important that the participatory oxygen in the leaching, being introduced in the form of oxygen or gas containing oxygen, must firstly dissolve into the solid-containing sludge, in order that the oxygen can participate in the leaching reactions of the solid matter. A tall reactor is used for the improvement of the dissolution of the oxygen, whereupon, as compared to normal atmospheric reactors, great hydrostatic pressure forms at the bottom of the reactor (1.5-3.0 atm, i.e. 0.15-0.30 MPa), due to which the oxygen dissolves well in the reaction solution and thereby catalyses the dissolution of the solid matter.
In the prior art it is known for example U.S. Pat. No. 4,648,973, wherein the equipment concerns a reactor with a height many times greater than its diameter, inside which is located a concentric pipe. The sludge is fed into the upper part of the central pipe, as is the oxygen. For recirculation of the sludge, the central pipe is equipped with a mixer suspended from the top downwards, which pumps the sludge down the central pipe and the sludge then passes up through the space between the reactor and the internal pipe. The ratio between the diameters of the central pipe and outer pipe is between 0.4 and 0.85.
Now, the developed invention relates to a method for leaching of solid matter from a sludge, such as metal concentrate with the aid of oxygen containing gas whereby the sludge is recirculated in a tall reactor. The height of the reactor is many times greater than its diameter and the reactor is equipped with a concentric central pipe extending to the bottom part, a mixer being located in the vicinity of the lower part of the central pipe and a feeding member for gas containing oxygen. The shaft of the mixer extends upwards from the bottom of the reactor. A sludge flow turning downwards is achieved with the aid of the mixer. The gas containing oxygen to be fed underneath the mixer is dispersed into the sludge in the form of small bubbles and at the same time the flow direction of the sludge is turned in the bottom part of the reactor to ascend upwards. Reactions between the solid matter containing sludge and the oxygen containing gas happen mainly either in the bottom part of the reactor or in a casing part between the reactor walls and the central pipe. The essential features of the present invention are laid out in the enclosed claims.
As mentioned above, it is essential to the method that the mixer is located in the immediate vicinity of the lower edge of the central pipe, whereby the cross-section area of the discharge orifice remaining between the central pipe and the mixer is less than half the cross-section area of the central pipe, preferably at most one third of the cross-section area of the pipe. Thus the flow rate, from the central pipe, of the downward-flowing sludge increases at least twofold in comparison to the flow rate taking place in the central pipe. The nearer the mixer is located to the lower edge of the pipe, the better the suction building up to the central pipe. In practice the limit is set by the tolerances, which result from the wearing of the shaft and from the flexibility and dimensioning of the other parts. At the aforementioned cross-sectional area ratio, such a flow rate is achieved that the downward-directed solution flow is faster than the ascending rate of the gas bubbles, and the upward flow rate of the solution in the annular casing of the reactor is greater than the settling rate of the particles of the solid matter.
The mixer used in the method according to the invention is of double-action, it is formed of two parts having an essentially horizontal plate between them. Curved blades are fixed above the horizontal plate which suck sludge downward in the central pipe. The blades fixed underneath the horizontal plate form a straight-bladed turbine mixer. As the gas containing oxygen is fed underneath the mixer installed in the bottom part of the reactor, the lower part of the mixer disperses the feed gas into very small bubbles, thus assisting the dissolution of the gas into the sludge. As the gas is fed into the sludge at the bottom part of the reactor, the gas bubbles moving with the sludge flow have as long a residence and reaction time in the sludge as possible, before they reach the surface or descend with the flow to be recirculated through the central pipe or are discharged through outlet means in the upper part of the reactor.
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Oinonen Yrjö
Takala Heikki
Hruskoci Peter A.
Morgan & Finnegan , LLP
Outokumpu Oyj
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