Method for the hydrogenation of nitriles to primary amines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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252477Q, 564491, 564493, C07C 8512

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active

043750036

ABSTRACT:
An improved process for preparing primary amines from an aliphatic nitrile and hydrogen utilizing a Raney cobalt catalyst which contains from about 2 to 35 weight percent of aluminum on a 100 weight percent total weight basis. Preferably, this catalyst is prepared under low temperature conditions from a cobalt-aluminum alloy. The process can be practiced continuously for extended periods of time at high reaction rates and high conversion yields even when employing concentrated nitrile starting feeds.

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patent: 3943171 (1976-03-01), Hoffmann et al.
patent: 3972940 (1976-08-01), Morgan, Jr.
patent: 4014820 (1977-03-01), Svarz et al.
Khim Prom. No. 7,399-401 (1958) By P. A. Moshkin et al.

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