Method for the hydrocarbylation of naphthoquinone derivatives

Details Method for the hydrocarbylation of naphthoquinone derivatives Method for the hydrocarbylation of naphthoquinone derivatives

1983-03-07

1985-03-26

Hollrah, Glennon H.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260687R, 2604297, 260448A, 2604293, 2604299, C07C 5012

Patent

active

045072418

ABSTRACT:
A method for the hydrocarbylation of naphthoquinones comprising cross-coupling addition of the hydrocarbyl moiety of selected organometallic reagents to leaving group-substituted naphthoquinones.

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Swenton et al., J. Am. Chem. Soc., 100, pp. 6182-6188 (1978).
Boehm et al., J. Medicinal Chem., pp. 295-299 (1981).
Wailes, Organometallic Chemistry of Titanium, Zirconium and Hafnium, 1974, p. 168, Academic Press, N.Y., N.Y.
Grignard, Rections of Nonmetallic Substances, Kharesch, 1954, pp. 530, 531, 536 & 537, Prentice-Hall Inc., N.Y. N.Y.
Negishi et al., Tet. Letter, 3737 (1981).
Kobayashi et al., JOC, 45, 5223 (1980).
Milstein et al., JOC 44, 1613, 1979.
Houben-Weyl, Methoden der Organischen Chem, 7/3a, Chinone I, Vierte Auflage, pp. 23 to 112.

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