Method for the hydration of acrylonitrile to acrylamide

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564128, C07C103133

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active

043025978

ABSTRACT:
In the reaction of conversion of nitriles to amides, more particularly, but not exclusively, acrylonitrile to acrylamide, the improvement consisting in the adoption, as a catalyst, of a copper-based catalyst which is prepared by reacting an organic copper chelate with aluminum-alkyl and/or an aluminum hydride. Higher yields and higher selectivity are obtained over the usual copper-based catalysts.

REFERENCES:
patent: 3032515 (1962-05-01), Hinsvark
patent: 3188230 (1965-06-01), Bakish et al.
patent: 3997606 (1976-12-01), Kane
patent: 4048226 (1977-09-01), Barber et al.

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