Method for the electrochemical conversion of a quadricyclane to

Details Method for the electrochemical conversion of a quadricyclane to Method for the electrochemical conversion of a quadricyclane to

1985-08-02

1986-04-15

Williams, Howard S.

Chemistry: electrical and wave energy

Processes and products

204231, 20415814, B01J 1912, C25B 300

Patent

active

045825785

ABSTRACT:
A method based on a cyclic single electron transfer mechanism has been developed for the electrochemical initiation and interruption of the exothermic quadricyclane to norbornadiene conversion.

REFERENCES:
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patent: 4446041 (1984-05-01), Neory
K. Maruyama et al., Chem. Letters, 839 (1981).
K. Maruyama et al., Chem. Letters, 1259 (1980).
R. W. Hoffmann et al., J. Chem. Soc. Chem. Commun. 345 (1983).
H.-D. Scharf et al., Angew. Chem. Int. Ed. Engl., 18, 652 (1979).
K. Maruyama et al., J. Org. Chem., 46, 5294 (1981).
C. Phillippopoulos et al., Ind. Eng. Chem. Prod. Res. Dev., 22, 627 (1983).
H. Hirao et al., J. Chem. Soc., Chem. Commun. 300 (1984).
P. Delahay, Instrumental Analysis, the Macmillon Co., (1957), pp. 118-139.

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