Method for the direct preparation of halogenated hydrocarbons by

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260449R, 260449M, 260653, 260664, C07C 1900, C07C 2706

Patent

active

040410870

ABSTRACT:
Halogenated hydrocarbons are selectively prepared under mild reaction conditions by flowing a gaseous mixture of H.sub.2, CO, and halogen selected from the group consisting of chlorine, bromine and iodine over a well-dispersed supported catalyst system, such as Pt/Re, Pt/Ir, Pt, Ir and Re on an acidic support such as Al.sub.2 O.sub.3, SiO.sub.2 -Al.sub.2 O.sub.3 or zeolites. The reaction occurs over a broad temperature range of from 200.degree. to 1,000.degree. C and a pressure of from 0.1 to 500 atmospheres.

REFERENCES:
patent: 3182092 (1965-05-01), Haszeldine et al.

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