Method for the control of the composition and physical propertie

Chemistry of inorganic compounds – Radioactive – Uranium compound

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423261, C01G 4301

Patent

active

058753850

ABSTRACT:
The present invention provides a method for varying and controlling the chemical composition and physical properties of the uranium oxide solids produced by the thermal conversion of UF.sub.6. The method allows the production of predominantly UO.sub.2, U.sub.3 O.sub.8, or UO.sub.3 interchangeably from the same reactor simply by controlling the hydrogen and oxygen contents of the feed relative to uranium. The temperature profile of the thermal reactor is established by specifying the preheat of the feed prior to mixing, the feed composition, and the reactor wall temperature to thus vary and control the physical properties of the resulting solids according to the end use of the uranium product.

REFERENCES:
patent: 3260575 (1966-07-01), Heestand et al.
patent: 3906081 (1975-09-01), Welty
patent: 3970581 (1976-07-01), Jeter et al.
patent: 4005042 (1977-01-01), Dada
patent: 4031029 (1977-06-01), Colter et al.
patent: 4090976 (1978-05-01), DeHollander et al.
patent: 4698214 (1987-10-01), Linz et al.
patent: 4830841 (1989-05-01), Urza
Richard L. Heestand, Thermal Chemical Reduction of Uranium Hexafluoride for the Direct Fabrication of Uranium Dioxide Ceramic Fuels, Dec. 1965, pp. 584-588, 1(6), Nuclear Applications
Irvin E. Knudsen, Engineering Development of Fluidized-Bed Fluoride Volatility Processes, ANL-6902, p. 1, Dec. 1964.

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