Method for the continuous production of aldehydes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C568S008000, C568S451000, C568S453000

Reexamination Certificate

active

07615645

ABSTRACT:
The invention relates to a method for the continuous production of aldehydes by the isomerising hydroformylation in a homogenous phase of olefin compositions by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. The production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to the method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2molar ratio of between 4:1 and 1:2 until a 40 to 95% conversion of the α-olefins is obtained.

REFERENCES:
patent: 3527809 (1970-09-01), Pruett et al.
patent: 4148830 (1979-04-01), Pruett et al.
patent: 4599206 (1986-07-01), Billig et al.
patent: 4668651 (1987-05-01), Billig et al.
patent: 4716250 (1987-12-01), Abatjoglou et al.
patent: 4769498 (1988-09-01), Billig et al.
patent: 4778929 (1988-10-01), Zehner et al.
patent: 4885401 (1989-12-01), Billig et al.
patent: 5728893 (1998-03-01), Becker et al.
patent: 5744650 (1998-04-01), Nicholson et al.
patent: 5808168 (1998-09-01), Bahrmann et al.
patent: 5849972 (1998-12-01), Vicari et al.
patent: 5874639 (1999-02-01), Nicholson et al.
patent: 6100432 (2000-08-01), Borgel et al.
patent: 6342605 (2002-01-01), Geissler et al.
patent: 6538168 (2003-03-01), Schwab et al.
patent: 6580009 (2003-06-01), Schwab et al.
patent: 6642420 (2003-11-01), Zehner et al.
patent: 6727391 (2004-04-01), Walczuch et al.
patent: 6737555 (2004-05-01), Maas et al.
patent: 6977312 (2005-12-01), Ahlers et al.
patent: 7015361 (2006-03-01), Zehner et al.
patent: 2004/0110960 (2004-06-01), Ahlers et al.
patent: 0 188 426 (1985-04-01), None
patent: 0 155 508 (1985-09-01), None
patent: 0 213 369 (1987-03-01), None
patent: 0 423 769 (1991-04-01), None
patent: 0 982 314 (2000-03-01), None
patent: 1 008 580 (2000-06-01), None
patent: 1 069 101 (2001-01-01), None
patent: 1 114 017 (2001-07-01), None
patent: 1 134 271 (2001-09-01), None
patent: 1 231 198 (2002-08-01), None
patent: 2000-143572 (2000-05-01), None
patent: WO-85/01567 (1985-04-01), None
patent: WO-97/20801 (1987-06-01), None
patent: WO-98/19985 (1998-05-01), None
patent: WO-98/52632 (1998-11-01), None
patent: WO-99/50214 (1999-10-01), None
patent: WO-99/52632 (1999-10-01), None
patent: WO-00/53546 (2000-09-01), None
patent: WO-01/58589 (2001-08-01), None
patent: WO-01/58844 (2001-08-01), None
patent: WO-02/068371 (2002-09-01), None
patent: WO02/068371 (2002-09-01), None
patent: WO-02/083695 (2002-10-01), None
d'Oro, Paolo Cavalier et al., “Propene Hydroformylation with Rhodium Carbonyls and Triphenylphosphine”, La Chimica et L'Industria 62 (1980), pp. 572-579.
Yang, Chao et al., “Kinetics of Hydroformylation of Propylene Using RhC1(CO)(TPPTS)2/TPPTS Complex Catalyst in Aqueous System”, Catalysis Today 74 (2002), pp. 111-119.
Reinius, H. K. et al., “The Effects of Process Variables in the Hydroformylation of Methyl Methacrylate with the In Situ Formed (o-thiomethylphenyl) diphenylphosphine Rhodium Complex”, Journal of Molecular Catalysis A: Chemical 158 (2000), pp. 499-508.
Weissermel, Klaus et al., Industrielle Organische Chemie, 5th Ed., Wiley-VCH, 1998, pp. 82-89.

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