Method for the concentration and separation of actinides from bi

Chemistry: analytical and immunological testing – Metal or metal containing – Zn – cd – hg – sc – y – or actinides – or lanthanides

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423 9, 422 70, 436175, 436161, 424 9, G01N 3320, G01N 3002, B01D 1100

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active

048351075

ABSTRACT:
A method and apparatus for the quantitative recover of actinide values from biological and environmental sample by passing appropriately prepared samples in a mineral acid solution through a separation column of a dialkyl(phenyl)-N,N-dialylcarbamoylmethylphosphine oxide dissolved in tri-n-butyl phosphate on an inert substrate which selectively extracts the actinide values. The actinide values can be eluted either as a group or individually and their presence quantitatively detected by alpha counting.

REFERENCES:
patent: 4162230 (1979-07-01), Horwitz et al.
patent: 4548790 (1985-10-01), Horwitz et al.
patent: 4574072 (1986-03-01), Horwitz et al.
N. A. Talvitie, Radiochemical Determination of Plutonium in Environmental and Biological Samples by Ion Exchange, Nov. 1971, pp. 1827-1830.
C. W. Sill et al., Simultaneous Determination of Alpha-Emitting Nuclides of Radium through Californium in Large Environmental and Biological Samples, Jul., 1979, pp. 1307-1314.

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