Method for the catalytic epoxidation of olefins with hydrogen pe

Details Method for the catalytic epoxidation of olefins with hydrogen pe Method for the catalytic epoxidation of olefins with hydrogen pe

1988-03-23

1989-07-04

Raymond, Richard L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

540145, C07D30112

Patent

active

048452521

ABSTRACT:
A method for the catalytic epoxidation of olefines with hydrogen peroxide in the presence of tungsten oxo complexes or of a binuclear compound of the type .mu.-oxobis [porphyrinato-oxo tungsten (V)] or cis-oxo peroxo tungsten (VI) prophyrin or cis-dioxo porphyrinatotungsten (VI) with octaethyl porphyrin or 5,10,15,20-tetraphenyl porphyrin or 5,10,15,20-tetra(4-pyridyl)-porphyrin as ligands.

REFERENCES:
Lendon, H. J.; Durbut, P, Varescon, F., J. Am Chem. Soc., 103 pp. 3601-3603 (1981).
Renaud, J-P, Battioni, P., Bartoli, J. F., Mansay, D., J. Chem. Soc. Chem. Commun., pp. 888-889 (1985).
Sheldon, R. A., J Mol. Cat., 7, pp. 107-126, (1980).

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