Method for synthesizing acyloxycarboxylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560 57, 560 58, 560 60, 560266, 558 6, 558 24, 558 28, 558 37, 558 46, 558 47, 558 56, 558 58, 558268, 558269, 558271, 2604105, 2604109R, C07C 6966

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050915606

ABSTRACT:
A method for synthesizing an acyloxycarboxylic acid by providing a reaction chamber, establishing sources of an .alpha.-hydroxycarboxylic acid and an acid chloride, and repeatedly contacting substantially equal molar amounts of the .alpha.-hydroxycarboxylic acid and the acid chloride within the reaction chamber. The acyloxycarboxylic acid so synthesized is useful as a starting material for conversion to various esters which, when placed in aqueous solution with a source of hydrogen peroxide, result in a peracid and are useful for bleaching applications.

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patent: 4036984 (1977-07-01), Takahashi
patent: 4085277 (1978-04-01), Harada
Morrison, "Derivatives of Carboxylic Acids", Organic Chemistry, Chapter 17, p. 476, 1959.

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