Method for synthesizing...

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters

Reexamination Certificate

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C558S122000, C562S019000

Reexamination Certificate

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07964750

ABSTRACT:
A method for synthesizing 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide or its derivatives has a step of introducing 6-chloro-6H-dibenz[c,e][1,2]oxaphosphorin or its derivative, an acid compound and water into a reacting chamber to form an organic layer having 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide or its derivative and an aqueous layer. Because the acid compound is from an external source and has a catalyzing effect, employing the method can prevent side reaction from occurring and increase yield of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide or its derivative. Furthermore, the method is a one-pot operation of hydrolysis, dehydration and cyclization, so the method does not require purification of intermediates. Therefore, the method is time- and cost-saving and requires less organic solvent, resulting in less pollution to the environment.

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Merriam-Webster Online Dictionary entry for “derivative”, (http://www.merriam-webster.com/dictionary/derivative), last accessed May 12, 2010.
Wang, Chun-Shan et al., Synthesis and properties of epoxy resins containing 2-(6-oxid-6H-debenz[c,e][1,2] oxaphosphorin-6-y1) 1,4-benzenediol, Polymer, vol. 39: pp. 5819-5826, 1998, Elsevier Science Ltd.

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