Method for stabilizing titania supported cobalt catalyst and the

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Silicon containing or process of making

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502325, B01J 2106, B01J 2374, B01J 2384

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active

051698218

ABSTRACT:
A method of preparing catalyst compositions of cobalt composited with ternary metal oxide supports of substituted titania having the general formula Co/Ti.sub.x M.sub.1-x O.sub.2 where x ranges from 0.01 to 0.14 and M is selected from the group consisting of silicon, zirconium, and tantalum and wherein the titania is an anatase polymorph stable under oxidative regeneration temperatures from about 400.degree. to about 750.degree. C.

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T. A. Egerton, et al., "XPS Analysis of Uncoated and Silica-Coated Titanium Dioxide Powders," 1983, pp. 311-323, Colloids and Surfaces, vol. 7.
Hideshi Hattori, et al., "The Nature of Active Sites on TiO.sub.2 and TiO.sub.2 -SiO.sub.2 for the Isomerization of Butenes," 1975, pp. 172-178, Journal of Catalysis, vol. 38.
D. N. Furlong, et al., "The Precipitation of Silica on Titanium Dioxide Surfaces," May 1979, pp. 409-419, Journal of Colloid and Interface Science, vol. 69.

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