Method for separation of isotopes

Gas separation: processes – Chromatography

Reexamination Certificate

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C095S088000, C096S101000

Reexamination Certificate

active

10518762

ABSTRACT:
This invention relates to a method for separation of isotopes, that is, to obtain isotopically pure fractions by separating natural 1 isotope mixtures in elements, where hydrogen is employed as ligand on the elements that are to be isotopically separated, and where the resulting compounds are gaseous at practical temperatures and pressures. More specific, the invention relates to a method for obtaining an isotopically pure 28SiH4 in industrial scale by separating the isotopes in a chromatographic column.

REFERENCES:
patent: 4010100 (1977-03-01), Suslick
patent: 4780116 (1988-10-01), Cheh et al.
patent: 6146601 (2000-11-01), Abesadze et al.
patent: 2003/0039865 (2003-02-01), Alexander et al.
patent: 61-107927 (1986-05-01), None
patent: 2001-199792 (2001-07-01), None
patent: 2001199792 (2001-07-01), None
patent: 2170609 (2001-07-01), None
Ullmann's Encyclopedia of Industrial Chemistry, Fifth, Compltely Revised Ed. , vol. A15, 1990, pp. 43-46.
Mills, “Silicon Isotope Separation by Distillation of Silicone Tetraflouride”, Separation Science and Technology 25(3) pp. 335-345, 1990.
Korolev, “Separation of Silicone Isotopes by Silicon Tetraflouride-Silicone Technology”, Inorganic Materials vol. 38, No. 6, pp. 539-541, 2002.

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