Method for separating fructose and glucose

Sugar – starch – and carbohydrates – Processes – Carbohydrate manufacture and refining

Reexamination Certificate

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C127S046100

Reexamination Certificate

active

07942972

ABSTRACT:
A process for separating fructose and glucose from mixtures of fructose and glucose from a liquid phase feed solution or a solid mixture containing the fructose and glucose is disclosed. The process implements ionic liquids as selective solvents that dissolve fructose and glucose in large quantities, but at different proportions which are then separated by filtration into a precipitate and a solution of ionic liquid enriched with the other sugar. The process also involves separation of the sugars from the ionic liquid enriched with the other sugar which is accomplished by one of various processes such as extraction with water in a centrifuge or cooling to reduce the solubility of sugar and then filtration. The ionic liquid is then recycled.

REFERENCES:
Kirk-Othmer Encylcopedia of Chemical Technology, “Extraction, Liquid-Liquid” (Jun. 2007), pp. 1-62.
Forsyth et al, “Ionic Liquids-An Overview”, Abstract Only, (2004).
Liu et al, “Room-temperature ionic liquids that dissolve carbohydates in high concentrations”, Green Chemistry, (2005) pp. 39-42.
Youngs et al, “Glucose Solvation by the Ionic Liquid . . .”, J. Phys. Chem. B (Nov. 2007) pp. 13765-13774.
Murugesan et al, “Ionic Liquids in Carbohydrate Chemistry—Current Trends and Future Directions”, Current Organic Synthesis, (2005), pp. 437-451.
Spear et al, “Ionic Liquids: Green Solvents for Carbohydrate Studies”, 2002 SPRI Conference Abstracts of Presentations, (Mar. 2002), Poster Abstract.

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