Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal
Patent
1982-01-13
1984-07-24
Padgett, Benjamin R.
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Radioactive metal
423 2, 423 8, C01G 5600, C01G 5700, C22B 6002
Patent
active
044617470
ABSTRACT:
A method for the separation of actinides from lanthanides present in a trivalent state in an acidic aqueous solution.
Said method consists in selectively extracting in an organic solvent the actinides present in said solution, by bringing said aqueous solution into contact with an organic solvent comprising a system of extractants constituted by an acidic organo-phosphorated compound containing at least one electron doner sulfur atom such as di-2-ethylhexyl-dithio-phosphoric acid, and by a neutral organophosphorated compound containing at least one electron-doner oxygen atom such as tributyl phosphate.
REFERENCES:
patent: 2905525 (1959-09-01), Dawson
patent: 4226791 (1980-10-01), Reinhardt et al.
patent: 4339416 (1982-07-01), Fitoussi et al.
Curtui, M., et al., "Solvent Extraction of Dioxouranium (VI) with Dialkylphorodithioic Acids-VI Synergic Effect of Triphenylphosphine Oxide", J. Inorg. Nucl. Chem., v. 43, pp. 1076-1078, 1981.
Fitoussi Richard
Musikas Claude
Ranarivelo Hubert
Commissariat a l''Energie Atomique
Padgett Benjamin R.
Thexton Matthew A.
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