Method for selectively hydrogenating a living polymer having ole

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253378, 5253379, 5253331, 5253332, 525338, C08F 804

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active

057537780

ABSTRACT:
There is provided a method for selectively hydrogenating living polymers having olefinic double bonds, in which the living polymers resulting from the polymerization initiated by alkyllithium compound are deactivated by contacting the polymerization terminators for a short time under a mild condition and hydrogenated in the presence of bis(cyclopentadienyl)titanium compound in high efficiency and high reproducibility without adjusting accurate molar ratio of the lithium compound to the titanium compound.

REFERENCES:
patent: 4501857 (1985-02-01), Kishimoto
patent: 4673714 (1987-06-01), Kishimoto
patent: 4980421 (1990-12-01), Teramoto
patent: 5039755 (1991-08-01), Chamberlain

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