Method for rosin esterification

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260106, C09F 104, C09F 700

Patent

active

046506071

ABSTRACT:
The catalytic combination of phosphinic acid (also called hypophosphorous acid) and a phenol sulfide compound is disclosed to accelerate the reaction rate of esterification of rosin with a polyhydric alcohol, as well as provide product color improvements. According to the process of the invention, a rosin is reacted with up to a 50% equivalent excess of the polyhydric alcohol in the presence of phosphinic acid and a phenol sulfide compound at a temperature of from about 180.degree. C. to about 300.degree. C.

REFERENCES:
patent: 3377334 (1968-04-01), McBride et al.
patent: 3417071 (1968-12-01), Wheelus
patent: 3423389 (1969-01-01), Wheelus
patent: 4548746 (1985-10-01), Duncan et al.

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