Method for rendering surface layer of limited play disk...

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Reexamination Certificate

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C428S064400, C428S064800, C430S270140

Reexamination Certificate

active

11209953

ABSTRACT:
An optically readable media (10) has an information-encoding layer (16) and at least one color-forming layer (12) that embodies an optical readout-limiting mechanism. In a first embodiment the at least one color-forming layer contains an additive that does not interfere with the optical readability of the media for a duration of a readout period. The additive, upon exposure to a source of optical radiation that is suitable for reversing the color-forming layer from an optical readout inhibiting state to an optical readout enabling state, undergoes a transformation that maintains the color-forming layer in the optical readout inhibiting state. More specifically, exposure to the source causes the color-forming layer to photobleach and the additive to oxidize, where the oxidation of the additive permanently inhibits the optical readability of the media. The additive may be a leuco dye. In one embodiment the color-forming layer is comprised of 3-[2,2-bis(4-diethylaminophenyl)vinyl]-6-dimethylaminophthalide and the additive is comprised of benzoyl leucomethylene blue. In a further embodiment the additive is placed into a protective layer (18) that overlies the color-forming layer.

REFERENCES:
patent: 5963536 (1999-10-01), Vasic et al.
patent: 6589626 (2003-07-01), Selinfreund et al.
patent: 6756103 (2004-06-01), Thompson et al.
patent: 6790501 (2004-09-01), van de Grampel et al.

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