Method for removing chromium from chromium containing waste mate

Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium

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C01G 3700

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active

050079603

ABSTRACT:
A method is provided for removing chromium from a chromium containing waste material wherein the waste material is dried by indirect heating, sized to a particle size of less than 0.105 mm, mixed with alkaline and oxidizing reactants, and reacted in a reaction vessel by indirect heating using approximately the stoichiometric oxygen requirement to form a reaction material containing water soluble chromates. The reaction material is cooled and resized, and then subjected to an aqueous solvent extraction to produce a solid phase containing substantially no chromium and an aqueous phase containing water soluble chromates. This aqueous phase is subjected to evaporation resulting in a concentrated chromate phase. The waste material has been rendered non-hazardous and the chromium has been recovered as useful chromates.

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"Chromate Chemical Production Industry: Waste Treatment Past and Present", T. McKee, New Jersey Dept. of Environmental Protection.

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