Method for removal of nickel and iron from alkali metal hydroxid

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Preparing inorganic compound

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205512, 205536, 210695, C25B 116

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active

061238260

ABSTRACT:
The present invention relates to a method to control of the presence of nickel and/or iron in a caustic solution using at least two magnets to remove about one third of the nickel and/or iron present in a caustic solution. The method involves passing cell liquor through a first magnet at a flow rate of about 600-900 gallons per minutes removing a significant amount of nickel and/or iron from the cell liquor forming first fluid, then evaporating a significant amount of water out of that first fluid and raising the temperature of that first fluid to above 330 F., then cooling the more concentrated caustic solution to a temperature of between about 75 and 100 F. forming a cooled solution, passing the cooled solution through a second magnet and removing additional nickel and/or iron forming a second cooled solution, filtering that second cooled solution forming a filtered solution, passing the filtered solution through an optional third magnet to remove remaining nickel and/or iron forming a substantially metal free caustic solution .

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OxyTech Systems, Inc. (Tilak Bommaraju & Paul Orosz), Caustic Evaporator Coorosion: Causes and Remedy, Mar. 1992, 15 pages.

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