Method for reducing unsaturation of polyethers

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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568865, 560198, C07C 6966

Patent

active

051030420

ABSTRACT:
Polyethers having terminal allyl unsaturation are subject to hydrogenolysis by reaction with a hydrogen donor in the presence of a n-allyl complex forming catalyst. The product polyethers have extremely low levels of unsaturation, and thus are useful in preparing polyurethanes having improved properties and processing.

REFERENCES:
patent: 3577559 (1971-05-01), Horsley
Tsuji, J. et al., Tetrahedron Letters, No. 7, pp. 613-616, 1979.
Hey, H. et al., Angew Chem. Intem., vol. 12 (1973), #11, pp. 928-929.
Yanada, T et al., Tetrahedron Letters, vol. 28, #39, pp. 4557-4560, 1987.

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