Method for recovery of alkali metal or alkaline-earth metal tere

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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562483, 562485, 562487, 562480, C07C 6748

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active

055457460

ABSTRACT:
An improved method for recovery of alkali metal or alkaline-earth metal terephthalate and of alkylene glycol, from polyalkylene terephthalate, in particular from polyethylene terephthalate (P.E.T.), alkylene glycol, in particular ethylene glycol produced in the form of vapor during the saponification reaction, initiated by the action of intensive kneading of polyalkylene terephthalate and the alkaline reagent at a temperature of 100.degree. to 200.degree. C. The alkylene glycol is recovered in gaseous form by entrainment by an inert gas or by extraction under low pressure. The alkaline terephthalate or alkaline-earth terephthalate is obtained in solid or powder form; it can easily be stored, transported and redissolved, in order to be purified and possibly transformed into terephthalic acid or ester.

REFERENCES:
patent: 3544622 (1970-12-01), England
patent: 4890996 (1990-01-01), Shimizu
patent: 5254666 (1993-10-01), Benzaria

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