Method for recovery of actinides from refractory oxides thereof

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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423250, 423251, 423258, 423252, C01G 5000, C01G 4306, C01F 1500

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active

047241276

ABSTRACT:
Method for recovery of actinides from nuclear waste material containing sintered and other oxides thereof using O.sub.2 F.sub.2 to generate the hexafluorides of the actinides present therein. The fluorinating agent, O.sub.2 F.sub.2, has been observed to perform the above-described tasks at sufficiently low temperatures that there is virtually no damage to the containment vessels. Moreover, the resulting actinide hexafluorides are not destroyed by high temperature reactions with the walls of the reaction vessel. Dioxygen difluoride is readily prepared, stored and transferred to the place of reaction.

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