Method for recovering casting refractory compositions from inves

Metal founding – Process – Including recycling of process material

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423 211, B02C 2320, C01F 1700

Patent

active

047995300

ABSTRACT:
A highly efficient method for recovering Y.sub.2 O.sub.3 from casting slurries and cores containing Y.sub.2 O.sub.3 in combination with a binder is disclosed. The slurry is first treated with a gelling agent which causes the slurry to gel. The gelled slurry is then ignited in order to remove residual organic compounds. After ignition, the product is crushed and pulverized to form a powder. Thereafter, the powder is calcined at a temperature sufficient to crystallize the silica binder in the powder. The calcined product is subsequently dissolved in a heated acid solution for a selected time period. The resulting solution contains dissolved Y.sub.2 O.sub.3 and undissolved binder residue, which is filtered and removed. The Y.sub.2 O.sub.3 in the solution is then diluted with deionized water, and precipitated, preferably using oxalic acid to produce yttrium oxalate. The yttrium oxalate is ultimately removed from the solution and calcined to produce high purity Y.sub.2 O.sub.3. Cores are processed in a similar manner.

REFERENCES:
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patent: 4703806 (1987-11-01), Lassow et al.
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Searle, Alfred B., "Refractory Materials: Their Manufacture and Uses", Charles Griffin & Co., Ltd., London, England, p. 122 (1917).
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Norton, F. H., "Refractories", McGraw-Hill Book Company, Inc., 3rd Ed., pp. 302-339 (1949).
Calvert, E. D., "An Investment Mold for Titanium Casting", Bureau of Mines Report of Investigation No. 8541 (1981).
Helferich, R. L. et al., "An Investigation of Yttrium Oxide as a Crucible Material for Melting Titanium", Dept. of Navy, Naval Ship Research & Development Center, Jan. 1973, Report 3911.
"Third Interim Technical Report Development of Titanium Alloy Casting Technology" Airesearch Mfg. Co. of AZ., Jan. 1975.

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