Method for reacting 2-aromatic substituted 1,3-dithianes with .a

Details Method for reacting 2-aromatic substituted 1,3-dithianes with .a Method for reacting 2-aromatic substituted 1,3-dithianes with .a

1976-07-23

1978-05-16

Jaisle, Cecilia M.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603305, 2603323R, 2603323H, 2603323P, 424277, C07D33908

Patent

active

040898768

ABSTRACT:
Method for reacting a 2-aromatic substituted 1,3-dithiane with an .alpha.,.beta.-unsaturated ketone to selectively produce either the 1,4-addition product or the 1,2-addition product and the products made thereby. The 1,2- and 1,4-addition products possess cardiovascular activity, particularly antihypertensive and antiarrythmic activity.

REFERENCES:
seebach, et al., J. Org. Chem., vol. 40, No. 2, 1975, pp. 231-237.
Bonnet, et al., C.A. 77:61307s (1972).
Trost, et al., J.A.C.S. 97:24, Nov. 26, 1975, pp. 7152-7157.

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